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Question

The cell reaction of the given galvanic cell,


Cu(s)|Cu2+(aq)||Hg2+(aq)|Hg(l) is:

A
Hg+Cu2+Hg2++Cu
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B
Hg+Cu2+Cu++Hg+
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C
Cu+HgCuHg
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D
Cu+Hg2+Cu2++Hg
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Solution

The correct option is D Cu+Hg2+Cu2++Hg
Cu(s)|Cu2+aq|anode|Hg2+|Hg(l)cathode
In anode oxidation takes place CuCu2++2e

In cathode reduction takes place Hg2++2eHg

Overall: Cu+Hg2+Cu2++Hg

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