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Question

The CFSE for octahedral [CoCl6]4 is 18000 cm1. The CFSE for tetrahedral [CoCl4]2 will be

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Solution

CFSE for octahedral and tetrahedral complexes are closely related to each other by formula, r=490.
where, 0=CFSE for octahedral complex, t=CFSE for tetrahedral complex
According to question, 0=18000cm1t=490=49×18000cm1 =4×2000cm1=8000cm1
Hence, correct choice is (c).


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