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Question

The change in the oxidation number of the underlined nitrogen atom in the following chemical reactions are :
a. Nitrous acid (HNO2) reduces MnO4 in acid solution.
b. Nitrous acid (HNO2) oxidises I to I2 in acid solution.

A
(a) +3 to +5
(b) +3 to +2
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B
(a) +3 to +6
(b) +3 to +2
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C
(a) +3 to +5
(b) +3 to +1
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D
(a) +3 to +2
(b) +3 to +5
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Solution

The correct option is B (a) +3 to +5
(b) +3 to +2
The balanced reactions are as follows:
i. 2MnO4+6H++5NO25NO3+3H2O+2Mn2+
ii. 2HNO2+2H+2I2NO+2H2O+I2
Oxidation number of N changes from +3 to +5 in (i).
Oxidation number of N changes from +3 to +2 in (ii).

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