The change in the oxidation number of the underlined nitrogen atom in the following chemical reactions are : a. Nitrous acid (HN––O2) reduces MnO⊖4 in acid solution. b. Nitrous acid (HN––O2) oxidises I⊖ to I2 in acid solution.
A
(a) +3 to +5 (b) +3 to +2
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B
(a) +3 to +6 (b) +3 to +2
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C
(a) +3 to +5 (b) +3 to +1
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D
(a) +3 to +2 (b) +3 to +5
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Solution
The correct option is B (a) +3 to +5 (b) +3 to +2 The balanced reactions are as follows: i. 2MnO⊖4+6H++5NO⊖2⟶5NO⊖3+3H2O+2Mn2+ ii. 2HNO2+2H⊕+2I⊖⟶2NO+2H2O+I2 Oxidation number of N changes from +3 to +5 in (i). Oxidation number of N changes from +3 to +2 in (ii).