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Question

The charge require to deposit 9 g of Al from Al3+ solution is: (At. wt. of Al=27.0)

A
3216.3 C
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B
96500 C
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C
9650 C
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D
32163 C
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Solution

The correct option is B 96500 C
Half Cell reaction:-
Al+3+3eAl(s).

(i) Mole ratio=molesofAlformedmolesofelectrons=13.
(ii) Moles of Al formed=Charge(Q)96500C/mole×moleratio.
WMM=Q(C)96500C/mole×13 [moles=WMM=Weightmolarmass].
927=Q(C)96500C/mole×13
Q(C)=9×96500×327=96500C.


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