The chlorination of toluene in the presence of light and heat followed by treatment with aqueous $N a O H$ gives:

o–Cresol

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p–Cresol

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2,4–Dihydroxy toluene

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Benzyl alcohol

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Solution

The correct option is D Benzyl alcohol
Chlorination in the presence of heat and light proceeds through free radical mechanism. Since the free radical is stabilised more at the benzylic position, chlorination takes places preferentially at the benzylic position.

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Q. Chlorination of toluene in the presence of light and heat followed by treatment with aqueous

N a O H

gives:

Q. Chlorination of toluene in presence of light and heat followed by treatment with aqueous NaOH gives:

Monochlorination of toluene in sunlight followed by hydrolysis with aq. NaOH yields
(a) o - cresol
(b) m - cresol
(c) 2, 4 - dihydroxytoluene
9d) benzyl alcohol

Chlorination of toluene in the presence of light and heat followed by treatment with aqueous NaOH gives

[IIT-JEE 1990]

Q. Chlorination of boiling toluene in the presence of light followed by treatment with aqueous

N a O H

gives:

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The chlorination of toluene in the presence of light and heat followed by treatment with aqueous NaOH gives:

The correct option is D Benzyl alcoholChlorination in the presence of heat and light proceeds through free radical mechanism. Since the free radical is stabilised more at the benzylic position, chlorination takes places preferentially at the benzylic position.

The chlorination of toluene in the presence of light and heat followed by treatment with aqueous $N a O H$ gives:

The correct option is D Benzyl alcohol
Chlorination in the presence of heat and light proceeds through free radical mechanism. Since the free radical is stabilised more at the benzylic position, chlorination takes places preferentially at the benzylic position.