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Question

The coefficient B in the virial equation of state has unit:


PVm=RT(1+BVm+CV2m+.....)

A
mole
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B
L/mole
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C
L-mole
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D
L
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Solution

The correct option is C L/mole
Unit of L.H.S = Unit of R.H.S
P:atm,Vm:L,R:Latm mole1K1
(Latm)=Latm mole1K1×K(1+B/L+C/L2+......)
mole=(1+B/L+C/L2+......)
The unit of B is Lmole, similarly for C is L2mole
Option B is correct.

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