The coefficient B in the virial equation of state has unit:
PVm=RT(1+BVm+CV2m+.....)
A
mole
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B
L/mole
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C
L-mole
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D
L
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Solution
The correct option is C L/mole Unit of L.H.S = Unit of R.H.S P:atm,Vm:L,R:L−atmmole−1K−1 (L−atm)=L−atmmole−1K−1×K(1+B/L+C/L2+......) mole=(1+B/L+C/L2+......) The unit of B is L−mole, similarly for C is L2−mole Option B is correct.