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Question

The color of KMnO4 is due to

A
dd transition
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B
Ligand to metal charge transfer
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C
Metal to ligand charge transfer
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D
None of the above
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Solution

The correct option is B Ligand to metal charge transfer
In KMnO4 Mn is in +7 oxidation state. So Mn has no d-electrons and thus possesses the tendency to accept electrons form the ligands. Due to this ligand to metal charge transfer, KMnO4 has a intense pink colour

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