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Question

The colourless and odourless gas (B) is:

A
CO
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B
CO2
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C
H2
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D
H2O
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Solution

The correct option is C H2


DU in A=(2nC+2)H2=(2×9+2)122=4

(It shows benzene ring which is also confirmed by the oxidation of (A) to benzoic acid (PhCOOH).)

i. Reaction of Na with (A) shows that it contains (-OH) group.

(A) is chiral, so the possible structures of (A) can be
(II) will give iodoform test.

But compound (A) does not give iodoform test. So the structure of (A) is (I).

339096_244557_ans_6818bb56a95846458f26e2c6c5fdbe32.png

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