The correct option is B Na3VO4
Compound with zero unpair electron will be colourless.
VCl3;23V3+;[Ar]183d2=2 unpaired electrons
VO+2;V4+;[Ar]183d2=1 unpaired electron.
[VO4]3−;V5+;[Ar]183d0= no unpaired electron so colourless.
[V(H2O)6]2+;V2+:[Ar]183d3=3 unpaired electrons.