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Question

The complex ion [NiF4]2+ is tetrahedral. Number of unpaired electrons present in the complex is/are:

A
2
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B
4
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C
1
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D
0
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Solution

The correct option is A 2

[NiF4]2+: In this coordination complex, Ni has the electronic configuration of 3d84s2 and N+2 has the electronic configuration of 3d84so.
Also, since fluorine is a weak ligand so, it will form an outer orbital complex with sp3 & tetrahedral geometry.
(Refer to Image)
It has 2 unpaired electrons.

1025439_166767_ans_f71d9b25a4734ef6b852eb2f14eda74d.PNG

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