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Question

The components of glassy bead C and brown bead D are, respectively:

A
NaBO2 and NiO
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B
B2O3 and Ni(BO2)2
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C
NaBO2 and NiB4O7
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D
B2O3 and NaBO2
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Solution

The correct option is D B2O3 and Ni(BO2)2
A is borax or sodium tetraborate (Na2B4O7.10H2O).
One mole of A contains 10 moles of water of crystallization.

It is a white crystalline solid and is used in water softening. Its aqueous solution is alkaline due to the formation of sodium hydroxide upon hydrolysis of Na2B4O7. The reaction is as follows:

Na2B4O7+7H2O2NaOH+4H3BO3

When borax is heated, it loses water and swells into a white mass which is B. The formula is Na2B4O7. The reaction is as follows:

Na2B4O7.10H2OheatNa2B4O7B+10H2O

On further heating, B forms glossy solid called borax glass and borax bead (compound C or B2O3). The reaction is as follows:

Na2B4O7heat2NaBO2+B2O3C

When C is heated with nickel oxide, a brown bead D is obtained which is nickel metaborate (Ni(BO2)2). The reaction is as follows:

B2O3+NiO(Ni(BO2)2)brown bead(D)

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