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Question

The composition of a sample of wustite is Fe0.93O1.00. What percentage of iron is present in the form of Fe III?

A
15%
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B
24%
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C
12%
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D
11%
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Solution

The correct option is A 15%
Oxidation no. of Fe in wustite is 200/93 = 2.15. It is an intermediate value between two oxidation state of Fe as, Fe (II) and (III)
Let percentage of Fe(III) be α, then
2 x ( 100 - α) + 3 x α = 2.15 x 100
α=15
or
Percentage of Fe(III) = 15%

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