The compound C3H4 has a triple bond, which is confirmed by its reaction with
A
Baeyers reagent
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B
Bromine in CCl4
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C
Ammonical silver nitrate
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D
All the above
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Solution
The correct option is D All the above Molecular formula C3H4 of a compound with a triple bond is CH3−C≡CH
Bromine in CCl4 is used to test for the presence of unsaturation in compound. Both alkene and alkyne will reacting with the bromine in CCl4, changing its color from an intense yellow to a colorless solution.
The Baeyer's test for unsaturation is for determining the presence of carbon-carbon double bonded and carbon-carbon trible bonded compounds.
Both these reagent cannot differentiate the double and triple bond in compound. So it won't confirm the triple bond in compound.
Terminal alkynes contain acidic hydrogen. These terminal alkynes react with ammoniacal solutions of silver nitrate to give white precipitate of silver alkynide. CH3−C≡CH+[Ag(NH3)2]+NO−3→CH3−C≡C−Ag+↓+NH+4NO−3+NH3