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Question

The compound having shortest S−O bond length is:

A
SO3F
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B
SO24
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C
SOF4
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D
SOCl2
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Solution

The correct option is A SO3F
Bond length is basically the average distance between nucleus of 2 bonded atoms in a molecule. The compound having shortest SO bond length is :
SO3F, as sulfur has 6 valance electrons and 5 of them are in bonding with oxygen and flourine is a strongly EN atom.
So, it attracts the electrons towards it strongly and reduces the bond length.

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