The compound which is insoluble in $d i l . H C l$ is :

M n S

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Z n s

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B a C O_{3}

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B a S O_{4}

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Solution

The correct option is D $B a S O_{4}$
$B a S O_{3}$ combines with $H C l$ aq to form $B a C l_{2} + H_{2} O$ and $S O_{2}$ but $B a S O_{4}$ is insoluble and does not react with $H C l$ as it is a salt of strong acid than $H C l$ .
Hence option D is correct.

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B a S O_{4}

B a S O_{4}

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