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Question

The compound which is not formed when a mixture of n-butyl bromide and ethyl bromide treated with sodium metal in presence of dry ether is :

A
butane
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B
octane
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C
hexane
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D
ethane
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Solution

The correct option is D ethane
The compound which is not formed when a mixture of n-butyl bromide and ethyl bromide treated with sodium metal in the presence of dry ether is ethane, CH3CH3.

The following products are obtained during the reaction.

2CH3CH2BrethylbromideNa−−−−dryetherCH3CH2CH2CH3butane

2CH3CH2CH2CH2BrnbutylbromideNa−−−−dryetherCH3CH2CH2CH2CH2CH2CH2CH3octane

CH3CH2CH2CH2Brnbutylbromide+CH3CH2BrethylbromideNa−−−−dryetherCH3CH3hexane

So, the corret option is D

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