The compound whose 0.1 M solution is basic is
Sodium acetate
0.1 M solution of sodium acetate is basic due to hydrolysis of acetate ion-
CH3COO− + H2O ⇌ CH3COOH + OH−
If the salt has a strong conjugate base, its solution will be basic. A similar logic could be extended to the acid. This is only with respect to SA + WB or WA + SB salt combinations.