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Question

The compounds formed at the anode in the electrolysis of an aqueous solution of potassium acetate, are ____________ respectively.

A
C2H6 and CO2
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B
C2H4 and CO2
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C
CH4 and H2
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D
CH4 and CO2
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Solution

The correct option is A C2H6 and CO2
Kolbe's electrolysis:

The Kolbe electrolysis or Kolbe reaction is an organic reaction named after Hermann Kolbe. The Kolbe reaction is formally a decarboxylative dimerisation of two carboxylic acids (or carboxylate ions) The overall general reaction is as shown in an image.

After electrolysis alkane is formed at anode along with the release of carbon-dioxide.
When potassium acetate (CH3COOK+) is used in electrolysis, carbon dioxide is released along with ethane (H3CCH3)
CH3COOCH3(radical)+CO2

CH3(radical)+CH3(radical)C2H6(ethane) is release at anode.
Option A is the correct answer.

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