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Question

The concentration of [H+] and concentration of [OH] of a 0.1 M aqueous solution of 2M ionised weak acid is: [ionic product of water =1×1014].

A
0.02×103M and 5×1011M
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B
1×103M and 3×1011M
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C
2×103M and 5×1012M
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D
3×102M and 4×1013M
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Solution

The correct option is A 2×103M and 5×1012M
Degree of ionization,
α=[H+]×100[HA]

[H+]=α×[HA]100

=2×0.1100

[H+]=2×103M.

KW=[H+][OH]

1014=2×103×[OH]

[OH]=10142×103

[OH]=5×1012M.

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