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Question

The conductivity of an aqueous solution of a weak monoprotic acid is 0.000032ohm1cm1 at a concentration 0.2M. If at this concentration, the degree of dissociation is 0.02, then the value of λ (equivalent conductance at infinite dilution in ohm1cm2/eqt) is :

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Solution

λm=0.0000320.2×103

α=0.02

α=λmλ

So, λ = 0.032×50.02=8

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