The conductivity of an intrinsic semiconductor depends on temperature as σ=σ0 e−ΔE/2KT, where σ0 is a constant. Find the temperature at which the conductivity of an intrinsic germanium semiconductor will be double of its value at T = 300 K. Assume that the gap for germanium is 0.650 eV and remains constant as the temperature is increased.
Since σ=σ0e−ΔE2KT
Given ΔE=0.650 eV, T=300 K
K=8.62×10−5 eV
According to question,
σ0e−ΔE2KT=2×σ0e−ΔE2×K×300
e−0.62502×8.62×10−5×T=e−0.6502×8.62×10−5×300
e−0.6502×8.62×10−5×T=6.96561×10−6
Taking 'ln' on both sides.
We get, −0.6502×8.62×10−5×7′=−11.874525
⇒ 1T′=11.874525×2×8.62×10−50.65
⇒ T′=317.51178=318 K