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Saturated,Unsaturated and Supersaturated Solutions

The conductiv...

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The conductivity of saturated solution of silver chloride is 1.24×10^6 S/cm. The ionic conductivity of Ag+ and Cl- at infinite dilution are 53.8 and 65.3 Scmsq/mol. Calculate the solubility of AgCl in gram per litre(g/lt).

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Q. The specific conductance of a saturated solution of AgCl at

25^{0}

C after subtracting the specific conductance of water is 2.28 x

10^{- 4} S m^{- 1}

. Calculate the solubility of AgCl in gram per

d m^{3}

at this temperature. The molar ionic conductances of

A g^{+}

C l^{-}

ions are 73.3 x

10^{- 4}

10^{- 4} S m^{2} m o l^{- 1}

. (Ag: 108 and Cl: 35.5).

The specific conductance of a saturated solution of silver chloride is $K Ω^{- 1} c m^{- 1}$ . The limiting ionic conductances of $A g$ $^{+}$ and $C l$ $^{-}$ ions are $x$ and $y$ , respectively. The solubility of silver chloride in g litre $^{- 1}$ is :

[Molar mass of $A g C l = 143.5$ ]

Q. The specific conductivity of a saturated solution of silver chloride is

2.30 \times 10^{- 6} m h o c m^{- 1}

25^{\circ} C

. Calculate the solubility of silver chloride at

25^{\circ} C

λ_{A g^{+}} = 61.9 m h o c m^{2} m o l^{- 1}

λ_{C l^{-}} = 76.3 m h o c m^{2} m o l^{- 1}

Q. The specific conductance of a saturated solution of silver chloride at

25^{o} C

after subtracting the specific conductance of water is

2.28 \times 10^{- 4} S m^{- 1}

. Calculate the solubility of silver chloride in grams per

d m^{3}

at this temperature.

$Λ_{m}^{0} (A g C l) = 138.3 \times 10^{- 4} S m^{2} m o l^{- 1}$
$M (A g C l) = 143.5 g m o l^{- 1}$

Q. The molar conductivities at infinite dilution of

A g N O_{3}

N a C l

are 116.0 and 110.0

S c m^{2} m o l^{- 1}

respectively. The conductivity of

A g C l

8.42 \times 10^{- 6} S c m^{- 1}

and of water used is

1.16 \times 10^{- 6} S c m^{- 1}

. The solubility of

A g C l

6.0 \times 10^{- 5} m o l / L

. Find the molar conductivity at infinite dilution of

N a N O_{3}

i n S c m^{- 1} m o l^{- 1}

) in the solution.

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