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Byju's Answer
Standard XII
Chemistry
Bronsted Lowry Theory
The conjugate...
Question
The conjugate base of
H
2
P
O
−
4
is:
A
H
P
O
2
−
4
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B
P
2
O
5
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C
H
3
P
O
4
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D
P
O
3
−
4
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Solution
The correct option is
A
H
P
O
2
−
4
The concept of conjugate Acid-Base pair was given by Lowry-Bronsted Theory.
According to the theory:
Acids are proton
(
H
+
)
donors.
Bases are proton
(
H
+
)
acceptors.
Hence, in order to get the conjugate base of a species, we should consider that substance as an acid and vice versa.
For example,
H
2
S
O
4
→
H
S
O
−
4
+
H
+
Therefore, conjugate base of
H
2
S
O
4
is
H
S
O
−
4
.
Using this logic, for the given example:
H
2
P
O
−
4
→
H
P
O
−
2
4
+
H
+
Hence, conjugate base of
H
2
P
O
−
4
is
H
P
O
−
2
4
.
Option A is correct.
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1
Similar questions
Q.
Three reactions involving
H
2
P
O
−
4
are given below:
(i)
H
3
P
O
4
+
H
2
O
→
H
3
O
+
+
H
2
P
O
−
4
(ii)
H
2
P
O
−
4
+
H
2
O
→
H
P
O
2
−
4
+
H
3
O
+
(iii)
H
2
P
O
−
4
+
O
H
−
→
H
3
P
O
4
+
O
2
−
Q.
Conjugate base of
H
3
P
O
4
?
Q.
Calculate
[
H
+
]
,
[
H
2
P
O
4
]
,
[
H
P
O
2
−
4
]
and
[
P
O
3
−
4
]
in a
0.01
M
solution of
H
3
P
O
4
.
Take
K
1
=
7.225
×
10
−
3
,
K
2
=
6.8
×
10
−
8
,
K
3
=
4.5
×
10
−
13
.
Q.
H
3
P
O
4
is a tribasic acid, it undergoes ionization as:
H
3
P
O
4
⇋
H
+
+
H
2
P
O
−
4
;
K
1
H
2
P
O
−
4
⇌
H
+
+
H
P
O
2
−
4
;
K
2
H
P
O
2
−
4
⇌
H
+
+
P
O
3
−
4
;
K
3
Then, equilibrium constant for the following reaction will be:
H
3
P
O
4
⇌
3
H
+
+
P
O
3
−
4
Q.
What is the
[
H
+
]
in 1M
H
3
P
O
4
if
H
3
P
O
4
⇌
H
+
+
H
2
P
O
−
4
K
a
1
=
10
−
4
H
2
P
O
−
4
⇌
H
+
+
H
P
O
−
2
4
K
a
2
=
10
−
9
H
P
O
−
2
4
⇌
H
+
+
P
O
3
−
4
K
a
3
=
10
−
13
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