The correct option is A exothermic change
The conversion of atomic hydrogen into an ordinary hydrgen is an exothermic reaction. Atomic hydrogens have excess energy and are highly unstable so when they combine to form a stable H2 molecule of low energy, it will release the excess energy in the form of heat. Hence it a exothermic reaction.
Exothermic reactions are reactions that release energy, usually in the form of heat or light.
2H→H2;ΔH=104.5 kcal