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Question

The coordination number of Co in [Co(en)2Cl2]Cl is:

A
3
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B
4
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C
5
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D
6
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Solution

The correct option is B 6
Co-ordination number is defined as the number of co-ordinate bonds (in the co-ordination sphere) of the central metal atom (Co) with the ligands (en and Cl).

In the given complex, Co binds with two a bi-dentate ligand en (2×2=4) and two mono-dentate ligand Cl (2×1=2).

Therefore, its co-ordination number is 4+2=6.

Hence, option D is correct.

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