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Question

The correct arrangement of the elements in the order of decreasing ionization energies is:

A
Na>Mg>Al
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B
Mg>Na>Al
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C
Al>Mg>Na
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D
Mg>Al>Na
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Solution

The correct option is D Mg>Al>Na
  • The general trend is forionization energy to increase moving from left to right across an element period. Moving left to right across a period, atomic radius decreases, so electrons are more attracted to the (closer) nucleus.
  • According to the trend the order of I.E will be Al>Mg>Na
  • But,its outer electron is in the 3p-orbital which is slightly further from the nucleus and is shielded by the 3s-orbital and is therefore requires less energy to remove than the magnesium's outer electron which is closer and not as shielded.
  • Hence the order is Mg>Al>Na

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