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Question

The correct boiling point order of Li,Na,K,Rb is:

A
Li>K>Na>Rb
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B
Na>Li>K>Rb
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C
Li>Na>K>Rb
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D
Rb>Na>K>Li
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Solution

The correct option is C Li>Na>K>Rb
The correct boiling point order is Li(1615K)>Na(1156K)>K(1032K)>Rb(961K).

As the atomic number increases, the van der Waals forces of attraction decreases and the boiling point decreases.

Hence, the correct option is C

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