The correct decreasing order of following alkyl halides according to the rate of β - elimination reaction with alcoholic KOH will be: (i)CH3−H|C|CH3−CH2Br (ii) CH3−CH2−Br (iii) CH3−CH2−CH2−Br
A
(i) > (ii) > (iii)
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B
(iii) > (ii) > (i)
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C
(ii) > (iii) > (i)
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D
(i) > (iii) > (ii)
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Solution
The correct option is B (i) > (iii) > (ii)
Stability of alkene after β-elimination directly depends on the number of β-substituents.
Since number of β- methyl substituent in (i) is 2, (iii) is 1 and (ii) is 0, thus the correct order of stability is:(i)>(iii)>(ii).