The correct increasing order of heat of hydrogenation for the following compounds is:
A
III<II<I
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B
I<II<III
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C
II<III<I
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D
III<I<II
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Solution
The correct option is AIII<II<I Calculating the number of α−hydrogens in each :
More the number of alpha hydrogens, more are the number of hyperconjugative structures, higher the stability of alkene and lesser is the heat of hydrogenation value.
Stability order : I<II<III
Heat of hydrogenation value order: III<II<I