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Question

The correct increasing order of heat of hydrogenation for the following compounds is:


A
III<II<I
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B
I<II<III
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C
II<III<I
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D
III<I<II
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Solution

The correct option is A III<II<I
Calculating the number of αhydrogens in each :


More the number of alpha hydrogens, more are the number of hyperconjugative structures, higher the stability of alkene and lesser is the heat of hydrogenation value.
Stability order :
I<II<III
Heat of hydrogenation value order:
III<II<I

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