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Question

The correct increasing order of the acidity of CO2,H2O and H2O2 is:

A
CO2<H2O2<H2O
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B
H2O<H2O2>CO2
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C
H2O<H2O2<CO2
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D
H2O2<H2O<CO2
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Solution

The correct option is C H2O<H2O2<CO2
An acid is a proton (hydrogen ion), donor.
A base is a proton (hydrogen ion), the acceptor.
H2O2 gives 2 hydrogen ions in aqueous solution whereas water gives 1 hydrogen ion. As H2O2 protonates to a larger extent than water in aqueous solution, hence, it has a larger Ka(acid dissociation constant), thus making it a stronger Bronsted-Lowry acid than water.
Hydrogen peroxide has a pH rating between 1 to 5 whereas carbon dioxide has a pH rating of 6. Therefore hydrogen peroxide is slightly more acidic than carbon dioxide.
The correct increasing order stands as H2O<H2O2<CO2.

Hence the correct answer is option (C).

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