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Question

The correct IUPAC name of HOCH2(CH2)3CH2COCH3 is:

A
2-oxoheptan-7-ol
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B
2-oxoheptanol
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C
3-hydroxyheptan-2-one
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D
7-hydroxyheptan-2-one
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Solution

The correct option is D 7-hydroxyheptan-2-one
By IUPAC rules,
1. Principle functional group must be included in the longest continuous carbon chain. Thus, ketonic group should be in the carbon chain.
2. As priority of -OH is less than -CO, -OH is considered as substituent and numbering should start from -CO.
Thus, we have -OH at 7th carbon and ketonic group at 2nd position.
Thus, the IUPAC of given compound is
7-hydroxyheptan-2-one
HOH27C6CH25CH24CH23CH22C1COH3

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