The correct option is D LiF<NaF<KF<RbF<CsF
As we move from top to bottom in the florides of alkali metals the solubility increases from Li to Cs, due to increase in the bond length and decrease in bond energy.
So the correct order of solubility of florides of alkali metals is LiF<NaF<KF<RbF<CsF
Hence option D is correct order.