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Question

The correct order of acidic strength of carboxylic acid is:

A
formic acid< benzoic acid< acetic acid
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B
formic acid< acetic acid < benzoic acid
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C
acetic acid< formic acid< benzoic acid
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D
acetic acid< benzoic acid< formic acid
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Solution

The correct option is B acetic acid< benzoic acid< formic acid
CH3 group shows +l effect and increases electron density on given. so, decreases acidic strength.
Ph group shows +R and I effect. So, it also increases electron density but less than R group. So, the order is
CH3COOH<PhCOOH<HCOOH

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