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Question

The correct order of basic strengths for the given compounds is:

A
R<P<Q
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B
Q<P<R
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C
P<R<Q
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D
Q<R<P
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Solution

The correct option is D Q<R<P
Due to ortho effect (steric inhibition to protonation), compound Q will be the weakest base. In both P and R, NO2 is at the para position which exhibits both R and I effects. Since the presence of two methyl groups at meta positions in P diminishes the R effect of NO2 makes it the strongest base.
Hence the order will be: Q<R<P

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