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Question

The correct order of bond angle is

A
PF3=PCl3=PBr3=PI3
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B
PF3<PBr3<PCl3<PI3
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C
PI3<PBr3<PCl3<PF3
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D
PF3<PCl3<PBr3<PI3
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Solution

The correct option is D PF3<PCl3<PBr3<PI3
The increasing order of the bond angles is PF3<PCl3<PBr3<PI3
As the electronegativity of the halogens decreases, the bond pair of electrons are more towards P atom. This increases the electron-electron repulsion between lone pair and bond pairs. Hence, the bond angle increases.

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