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Question

The correct order of bond length of the given species is:

A
CO23>CO2>CO
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B
CO2>CO>CO23
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C
CO>CO2>CO23
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D
None of these
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Solution

The correct option is A CO23>CO2>CO
CO bond order = 3
CO2 bond order = 2

CO23 bond order = 1.33 (due to resonance)

Bond length increases when bond order decreases. Hence, the correct order is:
CO23>CO2>CO

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