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Question

The correct order of C−O bond length is:

A
CO<CO23=CO2
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B
CO<CO3<CO2
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C
CO<CO2<CO23
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D
CO2<CO23<CO
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Solution

The correct option is C CO<CO2<CO23
The order is CO<CO2<CO23

CO: When drawing the lewis structure here, we end up with a triple bond between the carbon and the oxygen.

CO2: This lewis structure gives one double bond between each oxygen and the carbon.

CO23: When we draw the lewis structure for this ion, we get a double bond between one oxygen and the carbon, with single bonds between the other two oxygen atoms and the carbon. Because each of the oxygens wants a double bond to the carbon, they have resonating structures, meaning that in the end, we get a bond something between a double and a single bond for each Carbon-Oxygen bond. Therefore, this bond will be longer than a single bond, but shorter than a double bond.

And we know the order of bond length: Triple bond<double bond<single bond

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