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Question

The correct order of decreasing bond length of C=C in the above compounds is:
1101589_565d433c9c344c92b6110d0b7ca2f73f.png

A
II>I>IV>III
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B
III>II>I>IV
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C
IV>II>I>III
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D
none of the above
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Solution

The correct option is A II>I>IV>III
The bond length of C=C is affected by presence or absence of electron pushing group like CH3. Presence of methyl groups decrease the electron deficiency and the length of double bond thus increases. Similarly, presence of more double bonds has more electron attracting tendency of the bonds, due to which more double bonds cause shorter C=C.
Hence the decreasing bond length of C=C will be:
II>I>IV>III

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