The correct order of decreasing second ionization enthalpy of is:
(Ti=22,V=23,Cr=24,Mn=25)
A
Mn>Cr>Ti>V
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B
Ti>V>Cr>Mn
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C
Cr>Mn>V>Ti
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D
V>Mn>Cr>Ti
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Solution
The correct option is DCr>Mn>V>Ti The value is second IE generally increases towards the right in period, however Cr+ has 3d5 configuration which is extra-stable.
Hence 2nd IE of Cr is more than that of Mn. Thus correct order of 2nd IE is Cr>Mn>V>Ti