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Question

The correct order of first ionisation enthalpies of the following elements is:

A
Be>Mg>Ca>Sr>Ra>Ba
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B
Ra>Ba>Sr>Ca>Mg>Be
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C
Be>Mg>Ca>Sr>Ba>Re
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D
Ra>Sr>Ba>Mg>Ca>Be
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E
Be>Mg>Ca>Ra>Ba>Sr
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Solution

The correct option is C Be>Mg>Ca>Sr>Ra>Ba
Ionisation enthalpy decrease on going down the group.
So, IE1size
However, radium has exceptionally higher ionisation enthalpy in group 2.
The first ionisation enthalpy in kJmol1 of alkali metal and alkaline earth metals are as following:
Be=399;Mg=737
Ca=690;Sr=549
Ra=509;Be=503
Hence, order of ionisation enthalpy is
Be>Mg>Ca>Sr>Ra>Ba

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