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Question

The correct order of hydration energy of alkaline
earth metal is:

A
Be2+>Mg2+>Ca2+>Sr2+>Ba2+
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B
Ba2+>Be2+>Ca2+>Mg2+>Sr2+
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C
Mg2+>Be2+>Ba2+>Ca2+>Sr2+
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D
None
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Solution

The correct option is A Be2+>Mg2+>Ca2+>Sr2+>Ba2+
The hydration energies of alkaline earth metals decreases on moving down the group. The decreasing order is Be2+>Mg2+>Ca2+>Sr2+>Ba2+. All the alkaline earth metals have same charge. But the atomic size increases on moving down the group. Hence, the charge density decreases on moving down the group. This decreases the hydration energy.

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