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Question

The correct order of increasing [H3O+] in the following aqueous solution is:

A
0.01 M H2S<0.01 M H2SO4<0.01 M NaCl<0.01 M NaNo2
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B
0.01 M NaCl<0.01 M NaNO2<0.01 M H2S <0.01 M H2SO4
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C
0.01 M NaNO2<0.01 M NaCl<0.01 M H2S <0.01 M H2SO4
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D
0.01 M H2S<0.01 M NaNO2<0.01 M NaCl<0.01 M H2SO4
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Solution

The correct option is D 0.01 M H2S<0.01 M NaNO2<0.01 M NaCl<0.01 M H2SO4
Since, H2SO4 is stronger acid than HClHNO2H2S, [H3O+] will be highest for it. It will be followed by NaCl as it is a salt of strong acid & strong base. H2S will have the least [H3O+] concentration as it is a weaker acid.
Hence, the required order is:
0.01MH2S<0.01MNaNO2<0.01MNaCl<0.01MH2SO4

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