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Question

The correct order of increasing thermal stabilities of alkaline earth metal sulphates is:

A
SrSO4<CaSO4<MgSO4<BeSO4
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B
BeSO4<MgSO4<CaSO4<SrSO4
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C
CaSO4<BeSO4<MgSO4<SrSO4
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D
MgSO4<BeSO4<CaSO4<SrSO4
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Solution

The correct option is B BeSO4<MgSO4<CaSO4<SrSO4
The thermal stability of the sulphates of alkaline earth metals increase in the following order.
BeSO4<MgSO4<CaSO4<SrSO4
With increase in the atomic size the lattice energy increases as large size cation forms efficient close packing with large sulfate ion. Hence, the thermal stability increases.

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