The correct order of reactivity of aldehydes and ketones towards hydrogne cyanide is:
A
CH3COCH3>CH3CHO>HCHO
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B
CH3COCH3>HCHO>CH3CHO
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C
CH3CHO>CH3COCH3>HCHO
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D
HCHO>CH3CHO>CH3COCH3
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Solution
The correct option is DHCHO>CH3CHO>CH3COCH3
Aldehydes are more reactive towards HCN than ketones. In aldehydes lower the aldehyde or alkyl group higher the reactivity towards HCN. This is because of the low steric hindrance.