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Question

The correct order of reactivity of aldehydes and ketones towards hydrogne cyanide is:

A
CH3COCH3>CH3CHO>HCHO
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B
CH3COCH3>HCHO>CH3CHO
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C
CH3CHO>CH3COCH3>HCHO
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D
HCHO>CH3CHO>CH3COCH3
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Solution

The correct option is D HCHO>CH3CHO>CH3COCH3
Aldehydes are more reactive towards HCN than ketones. In aldehydes lower the aldehyde or alkyl group higher the reactivity towards HCN. This is because of the low steric hindrance.
Therefore order of reactivity is
HCHO>CH3CHO>CH3COCH3

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