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Question

The correct order of reactivity towards electrophilic substitution is:

A
benzene > phenol > benzoic acid > chlorobenzene
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B
phenol > benzene > chlorobenzene > benzoic acid
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C
chlorobenzene > benzoic acid > phenol > benzene
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D
benzoic acid > chlorobenzene > benzene > phenol
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Solution

The correct option is C phenol > benzene > chlorobenzene > benzoic acid
In general, electron releasing groups activate and electron withdrawing groups deactivate the benzene ring towards electrophilic substitution.

Hence, the correct order is:
C6H5OH>C6H6>C6H5Cl>C6H5COOH

Option B is correct.

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