wiz-icon
MyQuestionIcon
MyQuestionIcon
19
You visited us 19 times! Enjoying our articles? Unlock Full Access!
Question


The correct order of reactivity towards nucleophilic substitution reaction for the given compound is:

A
I>II>III
No worries! We‘ve got your back. Try BYJU‘S free classes today!
B
II>III>I
No worries! We‘ve got your back. Try BYJU‘S free classes today!
C
II>I>III
No worries! We‘ve got your back. Try BYJU‘S free classes today!
D
III>I>II
Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses
Open in App
Solution

The correct option is D III>I>II
Nitro group shows -I and -M both effects when attached to an aromatic system. More the δ+ charge at the leaving group, more favourable is the substitution.
(II) is least reactive as NO2 is at meta position to Cl and -M effect is hindered.
(I) and (III) both experience equal -M effect of NO2 but (III) has NO2 group nearer to Cl so -I effect is more pronounced there. Thus (III) becomes most reactive.

flag
Suggest Corrections
thumbs-up
0
Join BYJU'S Learning Program
similar_icon
Related Videos
thumbnail
lock
Mesomeric Effect
CHEMISTRY
Watch in App
Join BYJU'S Learning Program
CrossIcon