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Polyhalogen Compounds

The correct o...

Question

The correct order of stability of conformation of $N H_{2} - C H_{2} - C D_{2} - O H$ is:

A

Gauche > Anti > Eclipsed

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B

Anti > Gauche > Eclipsed

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C

Anti = Gauche > Eclipsed

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D

Gauche > Eclipsed > Anti

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Solution

The correct option is A Gauche > Anti > Eclipsed
Gauche form is more stable than anti-form because in gauche form intramolecular-H-bonding occurs between $N H_{2}$ and $O H$

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