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Question

The correct order of the lattice energies of the following ionic compounds is:

A
NaCl>MgBr2>CaO>Al2O3
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B
Al2O3>MgBr2>CaO>NaCl
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C
MgBr2>Al2O3>CaO>NaCl
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D
Al2O3>CaO>MgBr2>NaCl
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Solution

The correct option is D Al2O3>CaO>MgBr2>NaCl
As we move across the period,charge density of cation increases thus lattice energy increases.
Na+<Mg2+<Al3+
As we move down, the size increases which results in decrease of lattice energy.
Li+<Na+<K+
In this question, we have following cations (Na+,Mg2+,Al3+,Ca2+) which can be arranged according to their lattice energies as
Na+<Mg2+<Ca2+<Al3+
Therefore , order of lattice energy of ionic compound
Al2O3>CaO>MgBr2>NaCl

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