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Question

The correct order of thermal stability of alkaline earth metals carbonates is:

A
BaCO3<CaCO3<SrCO3<MgCO3
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B
MgCO3<CaCO3<SrCO3<BaCO3
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C
BaCO3<CaCO3<SrCO3<MgCO3
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D
MgCO3<CaCO3<SrCO3<BaCO3
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Solution

The correct option is B MgCO3<CaCO3<SrCO3<BaCO3
The thermal stability of alkaline earth metals carbonates increases down the group because down the group polarizing power of cation decreases. So thermal stability increases.
Hence, thermal stability order : MgCO3<CaCO3<SrCO3<BaCO3

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