The correct order of thermal stability of hydrogen halides (H – X) is
HF >HCl>HBr> HI
Thermal stability is directly proportional to bond dissociation energy and bond dissociation energy is inversely proportional to bond length. The decreasing order of bond dissociation energy is HF>HCl>HBr> HI and hence order of thermal stability is HF >HCl>HBr> HI.